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i believe that on windows the configuration is kept on the registry (and not on ~/.config/rncbc.org/Qsynth.conf file, as on *nix systems).

so try firing up regedit (or whatever it's the system registry editor utility nowadays) and search for "rncbc.org"/"Qsynth"; there you either turn or remove the offending setting out if you know what is, or just rip the "Qsynth" sub-tree branch off, as far to start/run qsynth.exe from scratch.

hth.
cheers